Silver trifluoromethanesulfonate 三氟甲烷磺酸银

规格: 98%
CAS: 2923-28-6
产品编号: H87360
MDL: MFCD00013226
品牌: INFI
Chemical NameSilver trifluoromethanesulfonate
CAS Number2923-28-6
Alfabeta NameSILVERTRIFLUOROMETHANESULFONATE
MDL NumberMFCD00013226
EC Number220-882-2
Beilstein Registry Number3598402
Synonym Trifluoromethanesulfonic acid (silver) {LY} Trifluoromethanesulfonic acid (silver) {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {} {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trifluoromethanesulfonic acid (silver) {} {} {} {} {} {}
PubChem Substance ID76223
Reaxys-RN3598402
Chemical Name Translation三氟甲烷磺酸银
InChIKeyQRUBYZBWAOOHSV-UHFFFAOYSA-M
LabNetwork Molecule IDLN00115656
InChIInChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
Canonical SMILESO=S(C(F)(F)F)([O-])=O.[Ag+]
GHS Symbol
Warnings LIGHT SENSITIVE, CORROSIVE
Signal word Warning
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
    Risk Statements
    • R34 Causes burns 会导致灼伤
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R50 Very toxic to aquatic organisms 对水生生物极毒
      Precautionary statements
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P302+P350
      • P302+P352
      • P302+P352+P332+P313+P362+P364
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P332+P313
      • P337+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P403+P233
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Packing GroupIII
          UN Number 3260 UN3260
          Storage condition RT, protect from light, stored under nitrogen {LY} RT, protect from light, stored under nitrogen {} {LY} RT, protect from light, stored under nitrogen {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {}
          Hazard Codes 8
        • {ALF} Silver salt soluble in ether, fairly soluble in benzene and toluene, less soluble in acetonitrile and insoluble in chloroform and dichloromethane; useful, e.g. in promotion of the leaving ability of halogens. For use in the conversion of alkyl halides to triflates, see: J. Chem. Soc., 173 (1956); J. Am. Chem. Soc., 90, 1598 (1968); Tetrahedron Lett., 3159 (1970); J. Chem. Soc., Perkin 1, 2887 (1980). Review: Synthesis, 85 (1982).
        • {ALF} For use as a catalyst for the oxy-Cope rearrangement of allyl alkynyl carbinols, where other silver salts are ineffective, see: Tetrahedron Lett., 25, 2873 (1984):
        • {ALF} Acyl halides are converted to acyl triflates, powerful acylating reagents, which can bring about Friedel-Crafts-type acylation without added Lewis acid catalyst: Chem. Ber., 116, 1195 (1983).
        • {ALF} Reaction with chlorosilanes gives silyl triflates, powerful silylating reagents, and, likewise trialkyltin halides are converted to the corresponding triflates: Chem. Ber., 103, 868 (1970).
        • {ALD} Beilstein:3(4)34
        • {SNA}
          • 2923-28-6 H87360 Silver trifluoromethanesulfonate 三氟甲烷磺酸银

          化学属性

          Mol. FormulaCAgF3O3S
          Mol. Weight256.94
          Melting Point283 - 289 °C(lit.)
          Density1.876
          TSCAT
          Stability易吸潮
          Appearance off-white pwdr.

          *以上化合物性质及应用等信息仅供参考