Dimethyl acetone-1,3-dicarboxylate 1,3-丙酮二甲酸二甲酯

规格: 95%
CAS: 1830-54-2
产品编号: H85100
MDL: MFCD00008462
品牌: INFI
Chemical NameDimethyl 1,3-Acetonedicarboxylate
CAS Number1830-54-2
Alfabeta NameDIMETHYLACETONEDICARBOXYLATE 13--,
MDL NumberMFCD00008462
Synonym Dimethyl acetone-1,3-dicarboxylate {LY} Dimethyl acetone-1,3-dicarboxylate {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetone-1,3-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetone-1,3-d
EC Number217-385-8
Beilstein Registry Number3(4)1817
PubChem Substance ID74591
Reaxys-RN1366042
Chemical Name Translation1,3-丙酮二羧酸二甲酯
InChIKeyRNJOKCPFLQMDEC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00195559
InChIInChI=1S/C7H10O5/c1-11-6(9)3-5(8)4-7(10)12-2/h3-4H2,1-2H3
Canonical SMILESC(C(CC(OC)=O)=O)C(OC)=O
GHS Symbol
Warnings IRRITANT
WGK Germany1
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H303 May be harmfully swallowed 吞食可能有害
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, Gloves
    Hazard Codes Xi
    Precautionary statements
    • P302+P352+P333+P313+P362+P364
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P333+P313
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P302+P350
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
    • P305+P351+P338
      Signal word Warning
      Risk Statements
      • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
        Safety Statements
        • S24 Avoid contact with skin 避免皮肤接触；
        • S37 Wear suitable gloves 戴适当手套；
        • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
          Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
        • {ALF} Reacts with ɑ-diketones in aqueous buffer to give bicyclic diketones (Weiss-Cook condensation): Tetrahedron Lett., 4885 (1968); Org. Synth. Coll., 7, 50 (1990):
        • {ALF} See also Diethyl­ acetone-1,3-dicarboxyl­ate, A10933.
        • {ALF} See also: J. Chem. Soc., Perkin 1, 1425 (1997). Use of cyclic ɑ-diketones leads to propellanes: Can. J. Chem., 189 (1978).
        • {ALF} The Na salt (NaH/THF) reacts with alkynals: J. Org. Chem., 62, 5688 (1997), or ynones: Synth. Commun., 28, 1525 (1998), under mild conditions to give 4-substituted dimethyl 2-hydroxyisophthalates via a Michael addition - aldol cyclization process; see 3-Butyn-2-one, L05527 for scheme.
          • 1830-54-2 H85100 Dimethyl acetone-1,3-dicarboxylate 1,3-丙酮二甲酸二甲酯

          化学属性

          Mol. FormulaC7H10O5
          Mol. Weight174.15
          Density1.18
          Refractive index1.4430 to 1.4460
          Boiling Point262.1°C at 760 mmHg
          Flash Point113 °C - 闭杯
          TSCAYes
          Melting Point16-17°C
          SolubilityAPPROX. 120 G/L (20 ºC)
          Appearance 无色或淡黄色液体, 密度1.185,沸点150℃(25 mmHg),折射率1.443-1.445,水溶性approx. 120 g/L

          *以上化合物性质及应用等信息仅供参考