tert-Butyl Isocyanide 异氰酸叔丁酯

规格: 95%
CAS: 7188-38-7
产品编号: H80658
MDL: MFCD00000002
品牌: INFI
Chemical Nametert-Butyl isocyanide
CAS Number7188-38-7
EC Number230-553-5
Beilstein Registry Number4,174
MDL NumberMFCD00000002
Reaxys-RN1815927
PubChem Substance ID23577
Synonym tert-Butyl isocyanide {LY} tert-Butyl isocyanide {} {LY} tert-Butyl isocyanide {} {} {LY} tert-Butyl isocyanide {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl isocyanide {} {} {} {} {} {} {} {
Chemical Name Translation异氰酸叔丁酯
InChIKeyFAGLEPBREOXSAC-UHFFFAOYSA-N
Wiswesser Line NotationNCX1&1&1
LabNetwork Molecule IDLN00226392
InChIInChI=1S/C5H9N/c1-5(2,3)6-4/h1-3H3
Canonical SMILESCC(C)([N+]#[C-])C
GHS Symbol
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 710 mg/m3/4H
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   33,241,1975

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 377 mg/m3/4H
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   33,241,1975

Signal word
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
    Risk Statements
    • R23 Toxic by inhalation 吸入有毒
    • R11 Highly flammable 非常易燃
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
      • P241+P242+P243
      • P242 Use only non-sparking tools. 只能使用无火花工具。
      • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
      • P303+P361+P353
      • P304+P340
      • P304+P340+P311
      • P305+P351+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P316
      • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
      • P370+P378
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        RTECSEQ7102500
        UN Number UN 1993 3/PG 2 1992 UN1992
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H330 Fatal if inhaled 吸入致命
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes F,T F;T
          Packing GroupII
          Hazard Class3/6.1
          Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Flammables area {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro
        • 用于香豆素，4H-吡喃和异恶唑啉的合成，也被用来捕捉2-亚环丙基-1,3 - 二酮。
        • {ALD} Beilstein:4,174
        • {ALF} Useful intermediate in multicomponent reactions. For example, forms a reactive 1 : 1 adduct with acetylenic esters, e.g. Dimethyl­ acetyl­enedicarboxyl­ate, A11437, which can be trapped with strong C-H acids, such as 4-Hydroxy-6-methyl-2-pyrone, L11457:
        • {ALF} In the presence of a free-radical initiator, can be used in a tin-free procedure for alkyl radical reactions: Angew. Chem. Int. Ed., 43, 3598 (2004).
        • {uni_hamburg} Short: II/19a
          • 7188-38-7 H80658 tert-Butyl Isocyanide 异氰酸叔丁酯

          化学属性

          Mol. FormulaC5H9N
          Mol. Weight83.13
          Density0.735
          Refractive indexn20/D 1.376(lit.)
          Boiling Point92°C
          Flash Point-2°C(lit.)
          TSCANo

          *以上化合物性质及应用等信息仅供参考