1-Hexanethiol 1-己硫醇

规格: 98%, SpcSeal
CAS: 111-31-9
产品编号: H72311
MDL: MFCD00004909
品牌: INFI
Chemical Name1-Hexanethiol
Synonym hexanethiolnormal n-thioheptylalcohol HEXYL MERCAPTAN 己硫醇 硫代己醇 1-Mercaptohexane Hexyl mercaptan MCH Mercaptan C6 Mercaptan C6 巯基己烷 hexylmercaptannormal hexylmercaptan(non-specificname) hexyl mercaptan hexyl hydrosulfide 1-hexanethiol N-HEXYL MERCAPTAN hexane-1-thiol Hexanethiol MERCAPTAN C6 1-Mercaptohexane 1-巯基己烷 MCH n-Hexylthiol 己硫醇;巯基己烷 Hexyl mercaptan 1-琉基乙烷 1-Hexanthiol 1-Hexyl mercaptan 1-Hexylthiol n-Hexanethiol 1-MERCAPTOHEXANE hexanethiol(non-specificname) hexan-1-thiol Hexylmercaptan 1-己硫醇 Hexan-1-thiol 1-hexylthiol 1-HEXANETHIOL FEMA 3842 1-己烷硫醇 hexylthiol USAF EK-4628 1-HEXYLMERCAPTAN Hexylthiol n-Hexyl mercaptan
CAS Number111-31-9
PubChem Substance ID87570549
EC Number203-857-0
Beilstein Registry Number1731295
MDL NumberMFCD00004909
Reaxys-RN1731295
Chemical Name Translation1-己硫醇
Wiswesser Line NotationSH6
LabNetwork Molecule IDLN00162980
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1080 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - respiratory stimulation
   Behavioral - somnolence (general depressed activity)
   Sense Organs and Special Senses (Eye) - lacrimation
REFERENCE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1254 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
   Behavioral - coma
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 396 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUT

WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H331 Toxic if inhaled 吸入中毒
  • H302 Harmful if swallowed 吞食有害
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes 3 Xn
    RTECSMO4550000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P241+P242+P243
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P312+P330
    • P301+P330+P331
    • P303+P361+P353
    • P304+P340
    • P304+P340+P311
    • P305+P351+P338
    • P308+P311
    • P309+P311
    • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
    • P370+P378
    • P403+P233
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger Warning
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
      • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
        Risk Statements
        • R10 Flammable 易燃
        • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          UN Number 1228 UN 1228 3/PG 2 UN3071
          Storage condition Flammables area 对空气敏感，密闭充氩保存。 Air Sensitive
          Packing GroupIII
          Hazard Class3/6.1
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 用于调节网络碳纳米管场效应晶体管的电特性。还用作铜表面的单分子层，以在铜暴露于环境中时延迟其?表面氧化，之后可通过在惰性 N2 中的退火步骤得到有效解吸，从而提供清洁的铜表面。
        • {uni_hamburg} Short: IV/18B
        • {ALD} Beilstein:1,408
        • {uni_hamburg} Short: IV/16
        • {uni_hamburg} Short: III/38B
          • 111-31-9 H72311 1-Hexanethiol 1-己硫醇

          化学属性

          Mol. FormulaC6H14S
          Mol. Weight118
          Refractive index1.4480 to 1.4520
          Boiling Point150-154
          Density0.838
          Melting Point-81 - -80
          Flash Point30°C(lit.)
          TSCAYes
          Solubility不溶于水，易溶于醇、醚。
          Stability对空气敏感

          *以上化合物性质及应用等信息仅供参考