包装 价格 库存 - 促销价
100mL    RMB   170
500mL    RMB   390
800mL    RMB   510
Borane-tetrahydrofuran complex	硼烷四氢呋喃

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  • Mol. Formula: BH3·C4H8O
  • Mol. Weight: 85.94
  • Density: 0.898
  • Flash Point: -22°C(lit.)
  • TSCA: Yes
  • Boiling Point: 66
  • Solubility: 起反应
  • Stability: 对空气敏感,对湿度敏感
Chemical NameBorane-tetrahydrofuran complex
Beilstein Registry Number3668402
MDL Number
PubChem Substance ID 87558653
Synonym
  • BORANE TETRAHYDROFURAN COMPLEX SOLUTION, ~1 M IN THF
  • TETRAHYDROFURAN BORANE
  • Borane tetrahydrofuran complex solution
  • 四氫喃硼烷
  • 四氢喃硼烷
  • 硼烷-四氢呋喃
  • BORANE
  • BORANE-TETRAHYDROFURAN COMPLEX, CA. 1.8M SOLUTION IN TETRAHYDROFURAN, TECH.
  • BTHF
  • Borane-tetrahydrofuran complex, 1M solution tetrahydrofuran
  • BORANE-TETRAHYDROFURAN COMPLEX, 1.5M SOL N IN TETRAHYDROFURAN AND ETHER, TECH.
  • BORANE-TETRAHYDROFURAN COMPLEX 1.0M SO&
  • BORANE TETRAHYDROFURAN COMPLEX
  • BORANE-TETRAHYDROFURAN
  • BORON HYDRIDE-TETRAHYDROFURAN COMPLEX
EC Number237-881-8
CAS Number14044-65-6
Reaxys-RN3668402
Chemical Name Translation硼烷四氢呋喃
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H351 Suspected of causing cancer 怀疑致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P231+232 Handle under inert gas. Protect from moisture. 在惰性气体中。防止受潮。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P210223231+232261370+378422
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+330+331+310
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P241+242+243
  • P261305+351+338
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+340+310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P335+334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. 刷掉皮肤松散颗粒。浸入冷水中/用湿绷带包扎
  • P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. 如果吞咽:漱口。不要催吐。
  • P308+311
  • P402+404 Store in a dry place. Store in a closed container. 存放在干燥的地方。贮存于密闭容器中。
  • P403+235 Store in a well-ventilated place. Keep cool. 存放在通风良好的地方。保持凉爽。
  • P303+361+353+310+363
  • P405 Store locked up. 上锁保管。
Signal word
Safety Statements
Packing GroupI
UN Number
Risk Statements
  • R11 Highly flammable 非常易燃
  • R22 Harmful if swallowed 吞咽有害
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Storage condition
  • 0-10
  • 0-10°C
  • Air & Moisture Sensitive
  • 储存温度2-8℃
  • 2-8°C
Hazard Codes
Hazard Class4.3/3
  • 用于将聚酰胺纤维表面的酰胺基还原为仲胺。
  • For other reactions of borane, see Borane-dimethyl­ sulfide complex, L07705.
  • Beilstein:17(3/4)24
  • Hydroboration, followed by reaction of the trialkylborane with a diazoketone to give a homologated ketone: Org. Synth. Coll., 6, 919 (1988). In situ generation of "disiamyl" borane from 2-methyl-2-butene, and use of this reagent in selective hydroboration reactions: Org. Synth. Coll., 7, 258 (1990). Preparation of di-3-pinanylborane from (-)-ɑ-pinene, and its use in asymmetric hydroborations, see: Org. Synth. Coll., 7, 339 (1990).
  • Examples of hydroboration reactions:
  • For use in the reduction of carboxylic acids to alcohols, see: Org. Synth. Coll., 7, 221 (1990).
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。