Borane pyridine complex 硼烷吡啶络合物

规格: 95%, SpcSeal
CAS: 110-51-0
产品编号: H64388
MDL: MFCD00012435
品牌: INFI
Chemical NameBorane pyridine complex
CAS Number110-51-0
EC Number203-773-4
Beilstein Registry Number3674913
MDL NumberMFCD00012435
Synonym Borane-pyridine complex {LY} Borane-pyridine complex {} {LY} Borane-pyridine complex {} {} {LY} Borane-pyridine complex {} {} {} {LY} Borane-pyridine complex {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-pyridine complex {} {} {} {}
PubChem Substance ID87564472
Reaxys-RN3674913
Chemical Name Translation硼烷吡啶络合物
Wiswesser Line NotationT6NJ XBHHHH
LabNetwork Molecule IDLN00164757
InChIKeyLPGWNCNRGQANGC-UHFFFAOYSA-N
Canonical SMILES[H-][B+3]([H-])([N]1=CC=CC=C1)[H-]
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 64800 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 95400 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 54 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

Signal word
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S15 Keep away from heat 远离热源；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R44 Risk of explosion if heated under confinement 密封下加热有爆炸危险
    • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
    • R10 Flammable 易燃
    • R26 Very toxic by inhalation 吸入极毒
    • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
    • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
    • R20 Harmful by inhalation 吸入有害
    • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
      Precautionary statements
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P305+P351+P338
      • P303+P361+P353
      • P332+P313
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P302+P350
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
      • P337+P313
      • P301+P310
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
        RTECSUS3675000
        Packing GroupII
        UN Number UN 1992 3/PG 2 UN2810 1992
        Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Air & Moisture Sensitive {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {}
        Hazard Codes T+ F;T+
        Hazard statements
        • H310+H330
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H301 Toxic if swallowed 吞食有毒
        • H330 Fatal if inhaled 吸入致命
        • H310 Fatal in contact with skin 皮肤接触致命
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
          Hazard Class3/6.1
        • 对非均相表面上气体吸收的托特等温线进行能量分布函数分析。
        • • α-烷基-β-羟基酯的制备
        • • 将短链寡核苷酸选择性的固定在丙烯酸共聚物凝胶中。
        • • 与病毒抗原配对的免疫球蛋白的制备
        • • 碳化硅的烧结
        • • 减少在对寡糖高效液相色谱分析中所使用的溶剂。
        • •催化油浆的改性影响到其碳化为中间相沥青的过程
        • {uni_hamburg} Short: II/19b
        • Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules
        • Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G.
        • Editor: Hüttner, W.
        • Source: Landolt-Börnstein, New Series
        • Volume: II/19b
        • Year: 1992
        • Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy
        • ISBN: 3-540-54578-6
        • ISBN: 978-3-540-54578-1
        • Internet Resource: DOI:10.1007/b44334
        • RefComment: XI, 488 pages.
        • Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
        • {uni_hamburg} Short: III/35A
        • Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31
        • Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A.
        • Editor: Gupta, R.R.; Lechner, M.D.
        • Source: Landolt-Börnstein, New Series
        • Volume: III/35A
        • Year: 1997
        • ISBN: 3-540-60366-2
        • ISBN: 978-3-540-60366-5
        • Internet Resource: DOI:10.1007/b53033
        • RefComment: VIII, 242 pages. With CD-ROM. Hardcover
        • Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 an
          • 110-51-0 H64388 Borane pyridine complex 硼烷吡啶络合物

          化学属性

          Mol. FormulaC5H8BN
          Mol. Weight92.93
          Density0.9
          Refractive index1.5290 to 1.5330
          Flash Point21 °C
          TSCAYes
          Boiling Point102 °C at 0.37505 mmHg
          Melting Point10 - 11 °C - lit.
          Solubility起反应 SLOWLY
          Stability对空气和水分敏感
          pH:A

          *以上化合物性质及应用等信息仅供参考