Ferric acetylacetonate 三乙酰丙酮铁

规格: 98%
CAS: 14024-18-1
产品编号: H63835
MDL: MFCD00000020
品牌: INFI
Chemical NameIron, tris(2,​4-​pentanedionato-​κO2,​κO4)​-​, (OC-​6-​11)​-
CAS Number14024-18-1
EC Number237-853-5
Beilstein Registry Number4157960
MDL NumberMFCD00000020
PubChem Substance ID87571482
Synonym (Acetylacetonato)iron(III) (OC-6-11)-tris(2,4-pent (OC-6-11)-tris(2,4-pentane dionato-O,o')-iron 2,4-Eisen(III)-acetylacetonat 2,4-Pentanedione, iron(III) derivative 2,4-Pentanedione; Ferric acetylacetonate; Ferric acetylacetonate; 2,4-Pentanedione, iron(III) derivative 2,4-戊二酸铁(III) 4-戊二酮-O Acetope Fe(II) Fe(acac)3 Ferric acetylacetonate Ferric tris(acetylacetonate) Iron (III) 2,4-pentanedionate Iron acetylacetonate Iron acetylacetone Iron tris(2,4-pentanedionato) Iron tris(acetoacetonate) Iron tris(acetylacetonate) Iron(3+) acetylacetonate Iron(III) acetylacetonateTris(acetylacetonato)iron(III) Iron, tris(2,4-pentane Tris(acetylacetonato)-eisen(III) Tris(acetylacetonato)iron
Chemical Name Translation三乙酰丙酮铁
Wiswesser Line NotationD6O-FE-O BDJ D1 F1 B-& BD6O-FE-O BDJ D1 F1 B-&BD6O-FE-O BDJ D1 F1
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 76 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CHTHBK Chemotherapy (Basel).  (S. Karger Pub., Inc., 79 Fifth Ave., New
   York, NY 10003) V.13-    1968-  Volume(issue)/page/year: 16,371,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02372

Signal word Warning
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
    Risk Statements
    • R22 Harmful if swallowed 吞咽有害
    • R36 Irritating to eyes 刺激眼睛
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P312+P330
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P332+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        RTECSNO8960000
        Hazard statements
        • H302 Harmful if swallowed 吞食有害
        • H319 Causes serious eye irritation 严重刺激眼睛
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Hazard Codes Xn
          Storage condition 密封保存
        • 用作树脂交联剂合固化促进基；橡胶添加剂；石油裂解催化剂；燃料油添加剂，可改善润滑性和燃烧性；有机合成催化剂。
        • {ALF} In combination with Na metal at room temperature in benzene, cyano groups are cleaved from alkyl nitriles to give the corresponding hydrocarbons: J. Am. Chem. Soc., 93, 7113 (1971).
        • {uni_hamburg} Short: III/5b
        • {ALF} Catalyzes the nitration of non-activated arenes, e.g. halogenobenzenes, and moderately activated arenes, e.g. alkylbenzenes and naphthalenes under non-acidic, non-aqueous conditions with NO2 in the presence of O2; no nitration occurs in the absence of the Fe(III) catalyst: J. Chem. Soc., Perkin 1, 2385 (1996).
        • {ALF} Catalyst for the coupling of Grignard reagents with aryl halides: J. Am. Chem. Soc., 124, 13856 (2002); Org. Lett., 6, 1227 (2004), with vinyl sulfones to give alkenes: Tetrahedron Lett., 23, 2469 (1982); Tetrahedron, 44, 111 (1988), and with acyl halides to give ketones in good yield: Tetrahedron Lett., 25, 4805 (1984). Alkenyl halides couple with aryl Grignards to give 1-aryl alkenes: Synlett, 1901 (2001). For leading references and improved reaction conditions for the coupling of alkyl and aryl Grignards with a varirtety of enol triflates and acid chlorides, and also for selective monoalkylation of dichlroarenes and heteroarenes, see: J. Org. Chem., 69, 3743 (2004).
        • {ALD} Beilstein: 1,IV,3675
          • 14024-18-1 H63835 Ferric acetylacetonate 三乙酰丙酮铁

          化学属性

          Mol. FormulaC15H21FeO6
          Mol. Weight353
          Density5.22
          Melting Point180 - 182 °C (dec.)(lit.)
          TSCAYes
          Solubility2 G/L (20 ºC)
          Stability易吸潮
          Boiling Point110°C 2mm

          *以上化合物性质及应用等信息仅供参考