Boron trifluoride acetic acid complex 三氟化硼乙酸络合物

规格: 33% BF3, SpcSeal
CAS: 373-61-5
产品编号: H58809
MDL: MFCD00036359
品牌: INFI
Chemical NameBoron trifluoride acetic acid
MDL NumberMFCD00036359
CAS Number373-61-5
PubChem Substance ID11116786
EC Number206-768-5
Beilstein Registry Number3686517
Synonym ACETIC ACID-BORON TRIFLUORIDE COMPLEX Aceticacidborontrifluoride(2:1) BORON TRIFLUORIDE DIACETIC ACID COMPLEX BORON TRIFLUORIDE-ACETIC ACID Borate(1-), bis(acetato-.kappa.O)difluoro-, hydrogen fluoride (1:2:1), (T-4)- Borate(1-),bis(acetato-O)difluoro-,dihydrogenfluoride,(T-4)- Boron trifluoride acetic acid complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation三氟化硼-乙酸
InChIKeyOVYKFNOIPQYMRU-UHFFFAOYSA-K
LabNetwork Molecule IDLN00223529
InChIInChI=1S/2C2H4O2.BF3/c2*1-2(3)4;2-1(3)4/h2*1H3,(H,3,4);
Canonical SMILESO=C(OB(F)(F)OC(C)=O)C.[F-].[H+]
GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Precautionary statements
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P305+P351+P338
      Signal word
      Packing GroupII
      UN Number
      Risk Statements
      • R22 Harmful if swallowed 吞咽有害
      • R34 Causes burns 会导致灼伤
        Safety Statements
        • S25 Avoid contact with eyes 避免眼睛接触；
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
          Storage condition Moisture Sensitive N/A N/A℃ No Data Available 避免潮湿。
          Hazard Codes C
        • {ALD} Beilstein: 2,IV,95
        • {ALF} Mild acid catalyst which has found use as a desilylating agent: Allylsilanes undergo desilylation, via ß-stabilized carbocations, to give alkenes with allylic rearrangement: Tetrahedron Lett., 446 (1979); J. Chem. Soc., Perkin 1, 3267 (1992). -Silyl tertiary alcohols undergo a pinacol-like rearrangement to give alkenes: Tetrahedron Lett., 22, 2321 (1981). Has been used in the protodesilylation of the phenyl group as part of the conversion of the dimethylphenylsilyl group into a hydroxyl group with retention of configuration: J. Chem. Soc., Perkin 1, 317 (1995). For reaction scheme, see Chlorodimethyl­phenyl­silane, A15638.
          • 373-61-5 H58809 Boron trifluoride acetic acid complex 三氟化硼乙酸络合物

          化学属性

          Mol. FormulaBF3 · 2CH3COOH
          Mol. Weight188
          Density1.353
          Refractive indexn20/D 1.368(lit.)
          Flash Point83°(181°F)
          TSCAYes
          Boiling Point
          Melting PointNo Data Available
          Solubility起反应
          Stability对湿度敏感

          *以上化合物性质及应用等信息仅供参考