包装 价格 库存 - 促销价
100mL    RMB   240
500mL    RMB   830
tert-Butyllithium
叔丁基锂

COA下载


  • Mol. Formula: C4H9Li
  • Mol. Weight: 64.06
  • Density: 0.69
  • Flash Point: -49°(-56°F)
  • TSCA: Yes
  • Vapor Density: ~3 (vs air)
  • Appearance: {Chemicalbook} 为无色或微黄色透明...
  • Boiling Point: 36-40
  • Stability: 对湿度,热和空气敏感
Chemical Nametert-Butyllithium
Synonym
  • 叔丁基锂, NOMINALLY 1.5M IN N-PENTANE
  • 叔丁基锂1.6M戊烷溶液
  • ButyllithiuminpentaneMslightlycloudyliq
  • TERT-BUTYLLITHIUM
  • 2-甲基-2-丙基锂
  • LITHIUM TERT-BUTYL
  • tert-butyl-lithium
  • 3-丁基锂
  • tert-Butyllithium
  • 叔丁基锂
  • 叔丁基锂 溶液
  • tert.-Butyl-lithium
  • (1,1-dimethylethyl)-lithiu
  • tert.-Butyllithium
  • T-BUTYLLITHIUM
  • Lithium,(1,1-dimethylethyl)-
  • tert-Butyl lithium
  • tert-Butyllithium,nominally1.5Minn-pentane
  • t-Butyllithium 16% in pentane (1-2M)
  • TERT-BUTYLLITHIUM, 1.7M SOLUTION IN PENT
  • Lithium-2-methyl-2-propanide, t-BuLi
  • tert-Butyllithium solution
  • TERT-BUTYLLITHIUM SOLUTION IN HEPTANE
  • TERT-BUTYLLITHIUM SOLUTION, ~1.5 M IN PE NTANE
  • 叔丁基锂 NOMINALLY 1.5M IN N-PENTANE, PACKAGED UNDER ARGON
  • t-butyl-lithium
  • T-BULI
  • Lithium, (1,1-dimethylethyl)-
  • t-Butyllithium
  • packagedunderArgoninresealableChemSealbottles
  • TERT-BUTYLLITHIUM 1.7 M IN PENTANE
  • Lithium, tert-butyl-
  • Lithium-tert-butyl
  • (1,1-Dimethylethyl)lithium
  • LITHIUM-2-METHYL-2-PROPANIDE
  • 第三丁基鋰 (須冷藏)
  • 1,1-Dimethyl-ethane-lithium
CAS Number594-19-4
EC Number209-831-5
Beilstein Registry Number4(3)2035
MDL NumberMFCD00008795
PubChem Substance ID 87560614
Reaxys-RN3587204
Chemical Name Translation叔丁基锂
InChIKeyBKDLGMUIXWPYGD-UHFFFAOYSA-N
Signal word
GHS Symbol
WGK Germany1
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R51/53
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R38 Irritating to skin 刺激皮肤
  • R50/53
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P231+232 Handle under inert gas. Protect from moisture. 在惰性气体中。防止受潮。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P210222223231+232370+378422
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P261305+351+338
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+334 IF ON SKIN: Immerse in cool water/wrap in wet bandages. 如果皮肤沾染:浸入冷水中/用湿绷带包扎
  • P335+334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. 刷掉皮肤松散颗粒。浸入冷水中/用湿绷带包扎
  • P301+310+331
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P304+340+310
  • P241+242+243
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P303+361+353+310+363
  • P301+330+331+310
  • P405 Store locked up. 上锁保管。
  • P402+404 Store in a dry place. Store in a closed container. 存放在干燥的地方。贮存于密闭容器中。
  • P233 Keep container tightly closed. ?保持容器密闭。
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
Personal Protective Equipment
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupI
UN Number
  • 3394
Storage condition
  • Air & Moisture Sensitive
  • 0-10°C
  • 0-10
  • 2-8°C储存,隔绝空气和水份
  • 储存温度2-8℃; 充氩保存
  • 2-8°C
Hazard Codes
  • F,C,N
Hazard Class4.2/4.3
  • ⑴. 叔丁基锂溶液暴露于空气或湿气时易起火。 ⑵.主要用于羰基化合物的烷基化、脱溴剂及有机合成。 ⑶. 用于重要的锂试剂。通过卤素一金属交换反应而可用于制备其它有机铿化合物,如芳基铿、三烷基氢化硼锉、乙烯基锉、a一铿烷基苯硫醚、β一铿代烯胺等。在温和条件下还原拨基成怒基也是聚合反应的引发剂。 ⑷.叔丁基锂相比正丁基锂和异丁基锂而言,具有更强的碱性和金属化活性以及更弱的亲核性,因此能够用于质子酸性更弱的烃类底物的脱质子锂化反应。通常,简单烷烃对于叔丁基锂仍然能保持惰性,但是对于含杂原子的溶剂如THF则会与叔 有机催化反应
  • Short: III/35C4
  • Short: EINECS
  • Short: III/5a
  • Beilstein:4(3)2035
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。