{ALF} Electron-deficient olefins undergo Rh-catalyzed 1,4-addition with Bis(pinacolato)­diboron, L16088, e.g. 2-cyclohexen-1-one to the ß-borylcyclohexanone: Tetrahedron Lett., 43, 2323 (2002):

{ALF} Homogeneous hydrogenation catalyst: J. Chem. Soc. (A), 1711 (1966), useful e.g. for the selective reduction of an unhindered alkene, of an unconjugated in the presence of a conjugated alkene: Org. Synth. Coll., 6, 459 (1988), or an alkene in the presence of a nitro-group: J. Org. Chem., 67, 3163 (2002). Hydroxyl groups protected as their allyl ethers may be deprotected by isomerization with Wilkinson's Catalyst to the more readily-hydrolyzed 1-propenyl ether: J. Org. Chem., 38, 3224 (1973).

{TRC} Evans, D.A. et al.: J. Am. Chem. Soc., 110, 6917 (1988); Ojima, I. et al.: Tetrahedron Lett., 13, 5035 (1972); Birch, A.J. et al.: Org. React., 24 (1976);

{uni_hamburg} Short: III/10b

{uni_hamburg} Short: EINECS

{ALF} Catalyst for hydrosilylation reactions, e.g. with Triethyl­silane, A10320, including ɑ&#

{ALF} Catalyst for hydrosilylation reactions, e.g. with Triethyl­silane, A10320, including ɑß-unsaturated ketones to silyl enol ethers, which can be hydrolyzed to saturated ketones: Organometallics, 1, 1390 (1982), and ɑß-unsaturated esters to silyl ketene acetals with high (Z)-selectivity: Synth. Commun., 17, 1 (1989).

{ALF} Homogeneous hydrogenation catalyst: J. Chem. Soc.(A), 1711 (1966), useful e.g. for the selective reduction of an unhindered alkene, of an unconjugated in the presence of a conjugated alkene: Org. Synth. Coll., 6, 459 (1988), or an alkene in the presence of a nitro group: J. Org. Chem., 67, 3163 (2002). Hydroxyl groups protected as their allyl ethers may be deprotected by isomerization with Wilkinson's Catalyst to the more readily-hydrolyzed 1-propenyl ether: J. Org. Chem., 38, 3224 (1973).

{ALF} Co-catalyst giving improved results in intramolecular Heck coupling reactions catalyzed by Pd(OAc)2: J. Org. C

{ALD}