2,4,6-Trifluorobenzeneboronic acid 2,4,6-三氟苯硼酸

规格: 97%
CAS: 182482-25-3
产品编号: H58458
MDL: MFCD01863169
品牌: INFI
Chemical Name2,4,6-Trifluorophenylboronic acid
CAS Number182482-25-3
Alfabeta NameTRIFLUOROPHENYLBORONICACID 246-,,
MDL NumberMFCD01863169
PubChem Substance ID160871045
Synonym 2,4,6-三氟苯硼酸 2,4,6-Trifluorophenylboronic acid
EC Number000-000-0
Beilstein Registry Number8549766
Chemical Name Translation2,4,6-三氟苯硼酸
Reaxys-RN8549766
GHS Symbol
Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
    Risk Statements
      Signal word
      Hazard statements
      • H315 Causes skin irritation 会刺激皮肤
        Precautionary statements
        • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
        • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
        • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
        • P332+P313
        • P305+P351+P338+P337+P313
        • P302+P350
        • P337+P313
        • P301+P312
        • P305+P351+P338
        • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P302+P352
        • {SA} 1. A. Adamczyk-Wozniak, et al., , Quantitative determination of the Lewis acidity of phenylboronic catechol esters - Promising anion receptors for polymer electrolytes Inorg. Chem. Commun. 14 , 1753-1755, (2011)
        • {SA} 2. B. M. Crowley, et al., , Expanding the scope of the Cu assisted Suzuki-Miyaura reaction Tetrahedron Lett. 52 , 5055-5059, (2011)
        • {SA} 3. T. Kinzel, et al., , A New Palladium Precatalyst Allows for the Fast Suzuki-Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids J. Am. Chem. Soc. 132 , 14073-14075, (2010)
        • {SA} 4. T. Korenaga, et al., , Rational electronic tuning of CBS catalyst for highly enantioselective borane reduction of trifluoroacetophenone Chem. Commun. 46 , 8624-8626, (2010)
        • {SA} 5. Y. Suzaki and K. Osakada, , Chemical Properties of Mononuclear and Dinuclear Phenylplatinum(II) Hydroxo Complexes with Cod Ligands. Transmetalation of Arylboronic Acids, Coupling of the Phenyl Ligands, and Carbonylation Organometallics 25 , 3251-3258, (2006)
        • {SA} 6. K. Osakada, et al., , Diarylpalladium Complexes with a Cis Structure. Formation via Transmetalation of Arylboronic Acids with an Aryliodopalladium Complex and Intramolecular Coupling of the Aryl Ligands, Affording Unsymmetrical Biaryls Organometallics 24 , 190-192, (2005)
          • 182482-25-3 H58458 2,4,6-Trifluorobenzeneboronic acid 2,4,6-三氟苯硼酸

          化学属性

          Mol. FormulaC6H4BF3O2
          Mol. Weight175.90
          Melting Point228-235
          TSCANo
          Density1.0

          *以上化合物性质及应用等信息仅供参考