(Acetylacetonato)dicarbonylrhodium(I) 二羰基乙酰丙酮铑 (I)

规格: 98%
CAS: 14874-82-9
产品编号: H56779
MDL: MFCD00009884
品牌: INFI
Chemical NameDicarbonylacetylacetonato Rhodium(I)
Synonym dicarbonyl(pentane-2,4-dionato-O,O')rhodium Acetylacetonatobis(carbonyl)rhodium Rhodium acetylacetonate dicarbonyl (Acetylacetonato)dicarbonylrhodium (I) Rhodium, dicarbonyl(2,4-pentanedionato-κO,κO' Dicarbonylacetylacetonatorhodium(I) (Acetylacetonato)dicarbonylrhodium(I) Rhodium(I) dicarbonyl acetylacetonate Dicarbonyl(2,4-pentanedionato)rhodium Dicarbonyl-acetylacetonato-rhodium(I) Dicarbonyl-(pentan-2,4-dionato)rhodium(I) Rhodium, dicarbonyl(2,4-pentanedionato)- Rh(CO)2acac 乙酰丙酮二羰基铑(I) 二羰基乙酰丙酮化铑(I) 二羰基乙酰丙酮铑(I) Dicarbonylacetylacetona Rhodium dicarbonylacetylacetonate Dicarbonylrhodium(I) acetylacetonate Rhodium biscarbonyl acetylacetonate
MDL NumberMFCD00009884
PubChem Substance ID24857317
CAS Number14874-82-9
EC Number238-947-9
Chemical Name Translation二羰基乙酰丙酮铑(I)
GHS Symbol
WGK Germany3
Precautionary statements
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H317 May cause an allergic skin reaction 可能导致皮肤过敏
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H301 Toxic if swallowed 吞食有毒
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      Hazard Codes T Xi
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Signal word Danger
      Safety Statements
        UN Number UN2926
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R25 Toxic if swallowed 吞咽有毒
        • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
        • R44 Risk of explosion if heated under confinement 密封下加热有爆炸危险
        • R11 Highly flammable 非常易燃
        • R36 Irritating to eyes 刺激眼睛
        • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
          Packing GroupII
        • {ALF}
        • {ALF} Miyaura has utilized this complex, in combination with a chelating phosphine ligand, for the conjugate addition of arylboronic acids to enones, to give saturated ketones: Organometallics, 16, 4339 (1997). Addition of aryl- and alkenylboronic acids to aldehydes to give secondary alcohols can also be brought about under similar conditions: Angew. Chem. Int. Ed., 37, 3279 (1998):
        • {ALF} An extension of these reactions to the addition of potassium alkenyl- and aryltrifluoroborates to aldehydes and enones has also been reported: Org. Lett., 1, 1683 (1999).
        • {uni_hamburg} Short: EINECS
        • {uni_hamburg} Short: IV/20B
        • {ALF} Catalyst for hydroformylation of alkenes with CO/H2 at atmospheric pressure to give enals: Angew. Chem. Int. Ed., 34, 1760 (1995).
        • {uni_hamburg} Short: III/5a
          • 14874-82-9 H56779 (Acetylacetonato)dicarbonylrhodium(I) 二羰基乙酰丙酮铑 (I)

          化学属性

          Mol. FormulaRh(CO)2(C5H7O2)
          Mol. Weight258
          Melting Point144-147°C subl.
          SolubilitySoluble in acetone
          TSCANo
          Density0.94
          Appearance greenish-red xtl.

          *以上化合物性质及应用等信息仅供参考