包装 价格 库存 - 促销价
100mL    RMB  1180
500mL    RMB  4850
Tributylborane
三丁基硼

COA下载


MSDS下载


  • Mol. Formula: [CH3(CH2)3]3B
  • Mol. Weight: 182.15
  • Density: 0.834 g/mL at 25 °C
  • Refractive index: 1.4285
  • Flash Point: -20°(-4°F)
  • TSCA: Yes
  • Boiling Point: 170°/222-225mm
  • Melting Point: -34°
  • Solubility: 不溶于水,溶于多数有机溶剂。
Chemical NameTributylborane
Synonym
  • Tributylborane1M solution in THFAcroSeal§3
  • Borane, tributyl-
  • TBB Tributylboron
  • Tri-n-butylboron
  • Tributylborine
  • Tributylborane
  • Tributyl borane
  • Tributylborane solution
  • Boronbutoxide
  • 三丁基硼烷
  • 三丁基硼烷 溶液
  • Tributylboron
  • TRIBUTYLBORANE, 1.0M SOLUTION IN DIETHYL ETHER
  • TBB
  • TRIBUTYLBORANE
  • 三正丁基硼
  • tributyl-boran
  • Tri-n-butyl borane
  • tributyl-borane
  • TRI-N-BUTYLBORON
  • tri-n-butylborane,tnbb
  • Tributylborane, 1M solution in THF
  • Tributylborane,98%
  • Borane,tributyl-
  • TRIBUTYLBORANE, 1.0M SOLUTION IN TETRAHY DROFURAN
  • tri-n-butylborane,
  • 三丁基硼
  • 1.0Msolutionintetrahydrofuran
  • Tri-n-butylborane
MDL NumberMFCD00009423
CAS Number122-56-5
PubChem Substance ID 24850833
EC Number204-554-6
Chemical Name Translation三丁基硼
Wiswesser Line Notation4B4&4
Beilstein Registry Number1738107
InChIKeyCMHHITPYCHHOGT-UHFFFAOYSA-N
WGK Germany1
RTECSED1850000
Packing GroupI
UN Number
  • UN2845
  • UN 2845 4.2/PG 1
Risk Statements
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R34 Causes burns 会导致灼伤
  • R22 Harmful if swallowed 吞咽有害
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
Storage condition
  • Flammables area
  • Air Sensitive
Precautionary statements
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P231 Handle under inert gas. 在惰性气体中操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P403+235 Store in a well-ventilated place. Keep cool. 存放在通风良好的地方。保持凉爽。
Signal word
  • Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
GHS Symbol
Personal Protective Equipment
  • Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Hazard Codes
  • F,Xn,C
  • F,C
Warnings
  • 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1125 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   NKOGAV Nippon Kokoka Gakkai Zasshi.  Journal of the Japanese Stomatological
   Society.  (Nippon Kokoka Gakkai, c/o Tokyo Daigaku Igakubu Koko Gekagaku
   Kyoshitsu, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113, Japan)  V.1-    1952-
   Volume(issue)/page/year: 22,533,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 104 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - hypermotility, diarrhea
   Lungs, Thorax, or Respiration - other changes
   Skin and Appendages - hair
REFERENCE :
   NKOGAV Nippon Kokoka Gakkai Zasshi.  Journal of the Japanese Stomatological
   Society.  (Nippon Kokoka Gakkai, c/o Tokyo Daigaku Igakubu Koko Gekagaku
   Kyoshitsu, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113, Japan)  V.1-    1952-
   Volume(issue)/page/year: 22,533,1973

  • ⑴. 合成苯基三烷基硼酸盐的添加反应。 ⑵. 用于产生取代的氮丙啶,恶唑烷和吡咯烷的基于硼的多组分反应。 ⑶. 与芳族醛亚胺的多组分C-烷基化反应;一锅烷基化和亲电取代。 ⑷. 用于有机反应和催化剂,在石油化学工业中也有应用。目前已发现含三丁基硼作为能化剂的树酯,对牙组织有良好的粘合性,且临床上亦无不良反应。
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/38A Title: Refractive Indices of Inorganic, Organometallic, and Organononmetallic Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38A Year: 1996 Keyword: organicmetallic compounds; inorganic compounds; refractive index; liquids; mixtures ISBN: 3-540-60539-8 ISBN: 978-3-540-60539-3 Internet Resource: DOI:10.1007/b55612 RefComment: VII, 400 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。