Chemical Name | Methylboronic Acid |
CAS Number | 13061-96-6 |
Alfabeta Name | METHYLBORONICACID |
MDL Number | MFCD00002105 |
Synonym |
Methaneboronic acid
dihydroxy-methyl-borane
methaneboronic acid
甲基硼酸
甲烷硼酸 |
Beilstein Registry Number | 1731087 |
PubChem Substance ID | 139377 |
Reaxys-RN | 1731087 |
EC Number | 250-023-7 |
Chemical Name Translation | 甲基硼酸 |
LabNetwork Molecule ID | LN00008674 |
InChI | InChI=1S/CH5BO2/c1-2(3)4/h3-4H,1H3 |
GHS Symbol
Warnings |
IRRITANT |
Precautionary statements | |
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
|
WGK Germany | 3 |
Signal word |
Warning |
Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
|
Hazard Codes |
Xi |
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37 Wear suitable gloves 戴适当手套;
|
Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
Storage condition |
Hygroscopic |
{uni_hamburg} Short: III/35A
Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31
Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A.
Editor: Gupta, R.R.; Lechner, M.D.
Source: Landolt-Börnstein, New Series
Volume: III/35A
Year: 1997
ISBN: 3-540-60366-2
ISBN: 978-3-540-60366-5
Internet Resource: DOI:10.1007/b53033
RefComment: VIII, 242 pages. With CD-ROM. Hardcover
Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
{uni_hamburg} Short: IV/20B
Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds
Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R.
Editor: Hall, K.R.
Source: Landolt-Börnstein, New Series
Volume: IV/20B
Year: 2000
Keyword: organic compounds; vapor pressure
ISBN: 3-540-64968-9
ISBN: 978-3-540-64968-7
Internet Resource: DOI:10.1007/b71424
RefComment: VII, 320 pages.
{SA}
1. Glasspoole, B. W.; et al., Suzuki-Miyaura cross-couplings of secondary allylic boronic esters Chem. Commun. 9th ed., 48 , 1230-1232, (2012) 摘要
{SA}
{SA} 2. Dai, H-X.; et al. , Divergent C-H Functionalizations Directed by Sulfonamide Pharmacophores: Late-Stage Diversification as a Tool for Drug Discovery J. Am. Chem. Soc. 18th ed., 133 , 7222-7228, (2011) 摘要
{SA}
{SA} 3. Inagaki, S.; et al., Selective heating of Pd-modified ordered mesoporous carbon CMK-3 by microwave irradiation Bull. C