Chemical Name | (4-Iodophenyl)boronic acid |
CAS Number | 5122-99-6 |
Alfabeta Name | IODOPHENYLBORONICACID 4- |
MDL Number | MFCD01319014 |
Synonym |
4-Iodophenylboronic acid
{LY} 4-Iodophenylboronic acid
{} {LY} 4-Iodophenylboronic acid
{} {} {LY} 4-Iodophenylboronic acid
{} {} {} {LY} 4-Iodophenylboronic acid
{} {} {} {} {LY} 4-Iodophenylboronic acid
{} {} {} {} {} {LY} 4-Iodophenylboronic acid
{} {} {} {} {} {} {LY} 4-Iodophenylboronic acid
{} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid
{} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid
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{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic a |
PubChem Substance ID | 151254 |
Chemical Name Translation | 4-碘苯硼酸 |
Reaxys-RN | 2936348 |
InChIKey | PELJYVULHLKXFF-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00008579 |
InChI | InChI=1S/C6H6BIO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H |
Canonical SMILES | IC1=CC=C(B(O)O)C=C1 |
Warnings |
IRRITANT |
WGK Germany | 3 |
GHS Symbol
Precautionary statements | |
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
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Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
|
Hazard Codes |
Xn
Xn,Xi
Xi |
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Signal word |
Warning |
Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
|
Risk Statements | |
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
Storage condition |
RT, protect from light
{LY} RT, protect from light
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{} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light
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{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect |
{SA}
1. Qi, Q.; Shen, Q.; Lu, L., Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) 摘要
{SA}
{SA} 2. Chen, M.; et al. , C-X (X=Br, I) Bond-Tolerant Aerobic Oxidative Cross- Coupling: A Strategy to Selectively Construct ß-Aryl Ketones and Aldehydes Adv. Synth. Catal. 2-3th ed., 354 , 341-346, (2012)
{SA}
3. Zhang, X.; et al. , An efficient and recyclable magnetic-nanoparticle-supported palladium catalyst for the Suzuki coupling reactions of organoboronic acids with alkynyl bromides Synthesis 18 , 2975-2983, (2011)
{SA}
4. Inamoto, K.; et al. , Micellar system in copper-catalyzed hydroxylation of arylboronic acids: facile access to phenols Chem. Commun. 42th ed., 47 , 11775-11777, (2011) 摘要
{SA}
{SA} 5. Tang, J-S.; et al. , Efficient palladium-catalyzed Suzuki-Miyaura cross-coupling of iodoethynes with arylboronic acids under aerobic conditions Synthesis 17 , 2789-2795, (2011)
{SA}
6. Matsuda, T.; et al. , Homocoupling of arylboronic acids catalyzed by simple gold salts Tetrahedron 37th ed., 52 , 4779-4781, (2011)
{SA}
7. Li, H.; et al. , Synthesis of arylketones by ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids Chem. Commun. 27th ed., 47 , 7880-7882, (2011) 摘要
{SA}
{SA} 8. Wang, S.; et al. , CuI-catalyzed Suzuki coupling reaction of organoboronic acids with alkynyl bromides Tetrahedron 26th ed., 67 , 4800-4806, (2011)
{SA}
9. Yahiaoui, S.; et al. , Chelation-Mediated Palladium(II)-Catalyzed Domino Heck-Mizoroki/Suzuki-Miyaura Reactions Using Arylboronic Acids: Increasing Scope and Mechanistic Understanding J. Org. Chem. 8th ed., 76 , 2433-2438, (2011) 摘要
{SA}
{SA} 10. Dickschat, A.; Studer, A., Radical Addition of Arylboronic Acids to Various Olefins und