4-Iodophenylboronic Acid 4-碘苯硼酸

规格: 97%
CAS: 5122-99-6
产品编号: H44934
MDL: MFCD01319014
品牌: INFI
Chemical Name(4-Iodophenyl)boronic acid
CAS Number5122-99-6
Alfabeta NameIODOPHENYLBORONICACID 4-
MDL NumberMFCD01319014
Synonym 4-Iodophenylboronic acid {LY} 4-Iodophenylboronic acid {} {LY} 4-Iodophenylboronic acid {} {} {LY} 4-Iodophenylboronic acid {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodophenylboronic a
PubChem Substance ID151254
Chemical Name Translation4-碘苯硼酸
Reaxys-RN2936348
InChIKeyPELJYVULHLKXFF-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008579
InChIInChI=1S/C6H6BIO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
Canonical SMILESIC1=CC=C(B(O)O)C=C1
GHS Symbol
Warnings IRRITANT
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
    • H302 Harmful if swallowed 吞食有害
    • H319 Causes serious eye irritation 严重刺激眼睛
      Hazard Codes Xn Xn,Xi Xi
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Signal word Warning
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S36 Wear suitable protective clothing 穿戴适当的防护服;
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
        Risk Statements
        • R22 Harmful if swallowed 吞咽有害
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition RT, protect from light {LY} RT, protect from light {} {LY} RT, protect from light {} {} {LY} RT, protect from light {} {} {} {LY} RT, protect from light {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect
        • {SA}
        • 1. Qi, Q.; Shen, Q.; Lu, L., Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) 摘要
        • {SA}
        • {SA} 2. Chen, M.; et al. , C-X (X=Br, I) Bond-Tolerant Aerobic Oxidative Cross- Coupling: A Strategy to Selectively Construct ß-Aryl Ketones and Aldehydes Adv. Synth. Catal. 2-3th ed., 354 , 341-346, (2012)
        • {SA}
        • 3. Zhang, X.; et al. , An efficient and recyclable magnetic-nanoparticle-supported palladium catalyst for the Suzuki coupling reactions of organoboronic acids with alkynyl bromides Synthesis 18 , 2975-2983, (2011)
        • {SA}
        • 4. Inamoto, K.; et al. , Micellar system in copper-catalyzed hydroxylation of arylboronic acids: facile access to phenols Chem. Commun. 42th ed., 47 , 11775-11777, (2011) 摘要
        • {SA}
        • {SA} 5. Tang, J-S.; et al. , Efficient palladium-catalyzed Suzuki-Miyaura cross-coupling of iodoethynes with arylboronic acids under aerobic conditions Synthesis 17 , 2789-2795, (2011)
        • {SA}
        • 6. Matsuda, T.; et al. , Homocoupling of arylboronic acids catalyzed by simple gold salts Tetrahedron 37th ed., 52 , 4779-4781, (2011)
        • {SA}
        • 7. Li, H.; et al. , Synthesis of arylketones by ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids Chem. Commun. 27th ed., 47 , 7880-7882, (2011) 摘要
        • {SA}
        • {SA} 8. Wang, S.; et al. , CuI-catalyzed Suzuki coupling reaction of organoboronic acids with alkynyl bromides Tetrahedron 26th ed., 67 , 4800-4806, (2011)
        • {SA}
        • 9. Yahiaoui, S.; et al. , Chelation-Mediated Palladium(II)-Catalyzed Domino Heck-Mizoroki/Suzuki-Miyaura Reactions Using Arylboronic Acids: Increasing Scope and Mechanistic Understanding J. Org. Chem. 8th ed., 76 , 2433-2438, (2011) 摘要
        • {SA}
        • {SA} 10. Dickschat, A.; Studer, A., Radical Addition of Arylboronic Acids to Various Olefins und
        • 5122-99-6 H44934 4-Iodophenylboronic Acid
4-碘苯硼酸

          化学属性

          Mol. FormulaC6H6BIO2
          Mol. Weight247.83
          Melting Point326-330°C
          Solubility25 g/L
          Boiling Point333.1°C at 760 mmHg
          Density1.0

          *以上化合物性质及应用等信息仅供参考