Tetrabutylammonium hydrogen sulfate 四丁基硫酸氢铵

规格: 99%
CAS: 32503-27-8
产品编号: H37197
MDL: MFCD00011637
品牌: INFI
Chemical NameTetrabutylammonium hydrogen sulfate
Synonym Tetrabutylammonium (hydrogensulfate) {LY} Tetrabutylammonium (hydrogensulfate) {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (hydrogensulfate) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (hydrogen
CAS Number32503-27-8
PubChem Substance ID87576671
Beilstein Registry Number3599663
EC Number251-068-5
MDL NumberMFCD00011637
Chemical Name Translation四丁基硫酸氢铵
Reaxys-RN3599663
InChIKeySHFJWMWCIHQNCP-UHFFFAOYSA-M
LabNetwork Molecule IDLN00190991
InChIInChI=1S/C16H36N.H2O4S/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1
Canonical SMILESCCCC[N+](CCCC)(CCCC)CCCC.O=S(O)([O-])=O
GHS Symbol
WGK Germany3
Hazard Codes Xn Xn,Xi Xi
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Gloves
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P312+P330
    • P302+P352+P332+P313+P362+P364
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P332+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Warning
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        Risk Statements
        • R22 Harmful if swallowed 吞咽有害
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
        • A compound that displays antibacterial properties
        • {ALF} For phase-transfer catalyzed conversion of nitriles to amides by alkaline H2O2, see: Synthesis, 243 (1980).
        • {ALF} In the dehydrohalogenation of aryl 2-haloethyl ethers to give vinyl ethers, this catalyst was found much more effective than the corresponding halides or benzyltriethylammonium salts: Synthesis, 688 (1979).
        • {ALF} Benzanilides have been N-alkylated in the presence of NaOH and K2CO3: Synth. Commun., 18, 2011 (1988).
        • {ALF} Widely used phase-transfer catalyst; see Appendix 2. Some illustrative applications are given below:
        • {ALF} The oxidation of primary alcohols to aldehydes by potassium chromate under phase-transfer conditions is better for higher homologues, where solubility in the aqueous phase is limited: Synthesis, 134 (1979). For phase-transfer catalyzed dichromate oxidation of secondary alcohols to ketones, see: Tetrahedron Lett., 1601 (1978).
        • {ALF} It was the most effective catalyst studied for the cyclization of ß-amino acids to ß-lactams by methanesulfonyl chloride and KHCO3: Chem. Lett., 443 (1981).
        • {ALF} For use in the permanganate oxidation of benzylic positions, see Potassium permanganate, A12170.
          • 32503-27-8 H37197 Tetrabutylammonium hydrogen sulfate 四丁基硫酸氢铵

          化学属性

          Mol. FormulaC16H37NO4S
          Mol. Weight339.53
          Melting Point167 - 173 ℃(lit)
          TSCAYes
          Density1.01
          Appearance 白色至类白色晶体，熔点 168-172°C，水溶性 Soluble
          SolubilitySoluble
          Stability对湿度敏感
          Boiling PointNo data available

          *以上化合物性质及应用等信息仅供参考