3-Picoline 3-甲基吡啶

规格: 99.5%
CAS: 108-99-6
产品编号: H30051
MDL: MFCD00006402
品牌: INFI
Chemical Name3-Methylpyridine
CAS Number108-99-6
Synonym 3-MethylPyridine(Picoline) 3-Methylpyidine 3-Methylpyridine 3-PICOLINE (3-METHYLPYRIDINE) 3-PICOLINE, 99.5+% 3-Picolin(ß) 3-Picolin(β) 3-methylpyridine 3-picoline (beta) 3-甲基吡啶 3-甲基吡啶 3-皮考林 3-甲基呲啶 m-Methylpyridine m-Picoline ?-Methylpyridine ?-Picoline B-Picoline BETAP NSC 18251 b-Picoline bPicolin beta-Methylpyridine m-Picoline pyridine, 3-methyl- pyridine,3-methyl- ß-Methylpyridine β-Methylpyridine β-picoline β-甲基吡啶 β-甲基吡啶,3-皮考林 β-皮考林
EC Number203-636-9
Beilstein Registry Number1366
MDL NumberMFCD00006402
PubChem Substance ID87574620
Merck Number7401
Reaxys-RN1366
Chemical Name Translation3-甲基吡啶
LabNetwork Molecule IDLN00223532
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   5,920,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LDLo - Lowest published let

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 596 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year:

Signal word Danger
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Risk Statements
    • R10 Flammable 易燃
    • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
    • R22 Harmful if swallowed 吞咽有害
    • R34 Causes burns 会导致灼伤
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241+P242+P243
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331+P310
      • P303+P361+P353
      • P305+P351+P338
      • P305+P351+P338+P310
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P403+P233
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H302 Harmful if swallowed 吞食有害
        • H311+H331
        • H302+H332
        • H311 Toxic in contact with skin 皮肤接触中毒
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          RTECSTJ5000000
          Packing GroupIII
          UN Number 2313 UN2313
          Hazard Codes 3 C Xn
          Hazard Class3
          Storage condition Flammables area
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 主要用于制造维生素B，烟酸，强心剂等，也可用作溶剂，酒精变性剂，各种中间体，杀虫剂
        • {TRC} Qiao, L., et al.: Bioorg. Med. Chem. Lett., 19, 6122 (2009),
        • {TRC} Farrer, N., et al.: Chem. Res. Toxicol., 23, 413 (2010),
        • {uni_hamburg} Short: III/20a
        • {uni_hamburg} Short: II/5
        • {ALD} Merck:14,7401
        • Beilstein:20,239
        • {TRC} Giri, A., et al.: Food Chem., 120, 621 (2010),
        • {uni_hamburg} Short: II/27B
        • {ALD} Merck:14,7401
          • 108-99-6 H30051 3-Picoline 3-甲基吡啶

          化学属性

          Mol. FormulaC6H7N
          Mol. Weight93.13
          Density0.957
          Refractive index1.5020 to 1.5090
          Autoignition Point~1000 °F
          Vapor Density3.2 (vs air)
          Boiling Point144
          Vapor Pressure4.4 mmHg ( 20 °C)
          Melting Point-19
          Flash Point36°C(lit.)
          TSCAYes
          Solubility溶于水、醇、醚，溶于多数有机溶剂。
          pH:A

          *以上化合物性质及应用等信息仅供参考