2-(Bromomethyl)benzeneboronic acid 2-(溴甲基)苯硼酸

规格: 97%
CAS: 91983-14-1
产品编号: H23937
MDL: MFCD01318941
品牌: INFI
Chemical Name2-(Bromomethyl)phenylboronic acid
CAS Number91983-14-1
Alfabeta NameBROMOMETHYLPHENYLBORONICACID 2-
MDL NumberMFCD01318941
Synonym 2-溴甲基苯基硼酸 α-Bromo-o-tolueneboronic acid o-Boronobenzyl bromide 2-(溴甲基)苯硼酸 2-(Bromomethyl)benzeneboronic acid 95% 2-Boronobenzyl bromide RARECHEM AH PB 0060 2-溴甲基苯硼酸 2-(Bromomethyl)phenylboronic acid 2-Bromomethylphenylboronic α-Bromo-o-tolueneboronic acid o-Boronobenzyl bromide 2-溴乙基基苯硼酸 2-(BROMOMETHYL)BENZENEBORONIC ACID 2-BROMOMETHYLPHENYLBORONIC ACID 2-溴苄苯硼酸
PubChem Substance ID125307977
Reaxys-RN2965283
Beilstein Registry Number16(4)1672
Chemical Name Translation2-(溴甲基)苯硼酸
GHS Symbol
Warnings IRRITANT
WGK Germany3
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P304+
    Signal word Warning {} {} {} {} {TCI}
    Hazard statements
    • H290 May be corrosive to metals 可能腐蚀金属。
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      Hazard Codes Xi
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Storage condition 0-10 0-10°C
      UN Number 3261
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S37 Wear suitable gloves 戴适当手套;
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Packing GroupIII
          Hazard Class8
        • {SA}
        • 1. M. Kitamura, et al., , 11B NMR Sensing of d-Block Metal Ions in Vitro and in Cells Based on the Carbon-Boron Bond Cleavage of Phenylboronic Acid-Pendant Cyclen (Cyclen = 1,4,7,10-Tetraazacyclododecane) Inorg. Chem. 50 , 11568-11580, (2011)
        • {SA}
        • 2. L. Feng, et al., , A highly sensitive water-soluble system to sense glucose in aqueous solution Org. Biomolecular Chem. 9 , 2938-2942, (2011)
        • {SA}
        • 3. Z. Sharrett, et al., , Boronic acid-appended bis-viologens as a new family of viologen quenchers for glucose sensing Tetrahedron Lett. 49 , 300-304, (2008)
        • {SA}
        • 4. S. Gamsey, et al., , Boronic Acid-Based Bipyridinium Salts as Tunable Receptors for Monosaccharides and a-Hydroxycarboxylates J. Am. Chem. Soc. 129 , 1278-1286, (2007)
        • {SA}
        • 5. D. E. Morrison, et al., , Boronated phosphonium salts containing arylboronic acid, closo-carborane, or nido-carborane: synthesis, x-ray diffraction, in vitro cytotoxicity, and cellular uptake J. Biol. Inorg. Chem. 15 , 1305-1318, (2010)
        • {SA}
        • 6. S. Kim, et al., , New fluorescent and colorimetric chemosensors based on the rhodamine and boronic acid groups for the detection of Hg2+ Tetrahedron Lett. 51 , 3286-3289, (2010)
        • {SA}
        • 7. Z. Xu, et al., , Ratiometric Fluorescence Sensing of Fluoride Ions by an Asymmetric Bidentate Receptor Containing a Boronic Acid and Imidazolium Group Eur. J. Org. Chem. 18 , 3058-3065, (2009)
        • {SA}
        • 8. X. Yu, et al., , Microwave-assisted synthesis and biological activities of 9-boronobenzyladenine derivatives J. Chem. Res. (M) 6 , 347-349, (2007)
        • 91983-14-1 H23937 2-(Bromomethyl)benzeneboronic acid
2-(溴甲基)苯硼酸

          化学属性

          Mol. FormulaC7H8BBrO2
          Mol. Weight214.85
          Melting Point145-148°
          TSCANo
          Density1.0

          *以上化合物性质及应用等信息仅供参考