Chemical Name | 2-(Bromomethyl)phenylboronic acid |
CAS Number | 91983-14-1 |
Alfabeta Name | BROMOMETHYLPHENYLBORONICACID 2- |
MDL Number | MFCD01318941 |
Synonym |
2-溴甲基苯基硼酸
α-Bromo-o-tolueneboronic acid o-Boronobenzyl bromide
2-(溴甲基)苯硼酸
2-(Bromomethyl)benzeneboronic acid 95%
2-Boronobenzyl bromide
RARECHEM AH PB 0060
2-溴甲基苯硼酸
2-(Bromomethyl)phenylboronic acid
2-Bromomethylphenylboronic
α-Bromo-o-tolueneboronic acid o-Boronobenzyl bromide
2-溴乙基基苯硼酸
2-(BROMOMETHYL)BENZENEBORONIC ACID
2-BROMOMETHYLPHENYLBORONIC ACID
2-溴苄苯硼酸 |
PubChem Substance ID | 125307977 |
Reaxys-RN | 2965283 |
Beilstein Registry Number | 16(4)1672 |
Chemical Name Translation | 2-(溴甲基)苯硼酸 |
Warnings |
IRRITANT |
WGK Germany | 3 |
GHS Symbol
Precautionary statements | |
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P304+P340
- P304+
|
Signal word |
Warning
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Hazard statements | |
- H290 May be corrosive to metals 可能腐蚀金属。
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
|
Hazard Codes |
Xi |
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Storage condition |
0-10
0-10°C |
UN Number |
3261 |
Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S37 Wear suitable gloves 戴适当手套;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
|
Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
Packing Group | III |
Hazard Class | 8 |
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1. M. Kitamura, et al., , 11B NMR Sensing of d-Block Metal Ions in Vitro and in Cells Based on the Carbon-Boron Bond Cleavage of Phenylboronic Acid-Pendant Cyclen (Cyclen = 1,4,7,10-Tetraazacyclododecane) Inorg. Chem. 50 , 11568-11580, (2011)
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2. L. Feng, et al., , A highly sensitive water-soluble system to sense glucose in aqueous solution Org. Biomolecular Chem. 9 , 2938-2942, (2011)
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3. Z. Sharrett, et al., , Boronic acid-appended bis-viologens as a new family of viologen quenchers for glucose sensing Tetrahedron Lett. 49 , 300-304, (2008)
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4. S. Gamsey, et al., , Boronic Acid-Based Bipyridinium Salts as Tunable Receptors for Monosaccharides and a-Hydroxycarboxylates J. Am. Chem. Soc. 129 , 1278-1286, (2007)
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5. D. E. Morrison, et al., , Boronated phosphonium salts containing arylboronic acid, closo-carborane, or nido-carborane: synthesis, x-ray diffraction, in vitro cytotoxicity, and cellular uptake J. Biol. Inorg. Chem. 15 , 1305-1318, (2010)
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6. S. Kim, et al., , New fluorescent and colorimetric chemosensors based on the rhodamine and boronic acid groups for the detection of Hg2+ Tetrahedron Lett. 51 , 3286-3289, (2010)
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7. Z. Xu, et al., , Ratiometric Fluorescence Sensing of Fluoride Ions by an Asymmetric Bidentate Receptor Containing a Boronic Acid and Imidazolium Group Eur. J. Org. Chem. 18 , 3058-3065, (2009)
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8. X. Yu, et al., , Microwave-assisted synthesis and biological activities of 9-boronobenzyladenine derivatives J. Chem. Res. (M) 6 , 347-349, (2007)