Chemical Name | 4-Oxotetrahydropyran |
CAS Number | 29943-42-8 |
Alfabeta Name | TETRAHYDROPYRANONE H44---- |
MDL Number | MFCD00006581 |
Synonym |
四氢吡喃酮
四氢-4H-吡喃-4-酮 |
PubChem Substance ID | 87577539 |
Beilstein Registry Number | 17(5)9,21 |
EC Number | 249-967-2 |
Chemical Name Translation | 四氢-吡喃-4-酮 |
Reaxys-RN | 106463 |
InChIKey | JMJRYTGVHCAYCT-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00008011 |
Warnings |
IRRITANT |
WGK Germany | 3 |
Hazard statements | |
- H226 Flammable liquid and vapour 易燃液体和蒸气
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Signal word |
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GHS Symbol
Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Safety Statements | |
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Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Precautionary statements | |
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
- P233 Keep container tightly closed. ?保持容器密闭。
- P403+P235
- P241+P242+P243
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Packing Group | III |
UN Number |
1224 |
Storage condition |
储存温度2-8°C |
Hazard Class | 3 |
Hazard Codes |
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{ALF} The methyl enol ether is a useful protecting agent for alcohols, e.g. in nucleotide synthesis, with the advantage over 3,4-Dihydro-2H-pyran, L02731, that no new asymmetric center is introduced on reaction with a chiral alcohol: J. Am. Chem. Soc., 89, 3366 (1967); Tetrahedron, 26, 1023, 1031 (1970).
{ALD} Beilstein:17(5)9,21