包装 价格 库存 - 促销价
100mL    RMB   180
500mL    RMB   470
1L       RMB   840
Boron trichloride
三氯化硼

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  • Mol. Formula: BCl3
  • Mol. Weight: 117.17
  • Boiling Point: 12.5 °C(lit.)
  • Melting Point: -107 °C(lit.)
  • Density: 0.909 g/mL at 25 °C
  • TSCA: Yes
  • Vapor Density: 4.05 (vs air)
  • Vapor Pressure: 29.72 psi ( 55 °C)
  • Flash Point: 2°C(lit.)
  • Solubility: 分解
  • Stability: 对热、湿度及空气敏感
Chemical NameBoron trichloride
CAS Number10294-34-5
PubChem Substance ID 24885451
EC Number233-658-4
MDL NumberMFCD00011313
Reaxys-RN3903057
Merck Number1348
Synonym
  • BCl3
  • {uni_hamburg}
  • Trichloroborane
  • BCl3
  • Boron chloride
  • Borane, trichloro-
  • Boron chloride (BCl3)
  • Borane,trichloro-
  • Trichloroboron
  • BORON TRICHLORIDE, 10 WT. % SOLUTION IN 2-CHLOROETHANOL
  • 氯化硼
  • BORON TRICHLORIDE, 1.0M SOLUTION IN HEXA NES
  • 三氯化硼
  • chloruredebore
  • chloruredebore(french)
  • boron (III) chloride
  • 三氯硼烷
  • boron trichloride
  • BORON TRICHLORIDE, 1.0M SOLUTION IN DICH LOROMETHANE
  • BORON TRICHLORIDE, 1.0M SOLUTION IN HEPT ANE
  • BORON TRICHLORIDE, 1.0 M SOLUTION IN TO&
  • trichloro-Boron
  • BORON TRICHLORIDE, 1.0M SOLUTION IN P-XY LENE
  • trichloro-boran
  • boronchloride(bcl3)
  • Trichlorboran
  • Trona boron trichloride
  • 三氯化硼 溶液
  • Bortrichlorid
  • 电子工业用三氯化硼
  • BORON TRICHLORIDE
  • Chlorure de bore
Beilstein Registry Number2384789
Chemical Name Translation三氯化硼
Wiswesser Line NotationGBGG
GHS Symbol
WGK Germany3
Hazard Codes
  • F,T+,N
  • F,T+
  • T+
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H300 Fatal if swallowed 吞食致命
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H351 Suspected of causing cancer 怀疑致癌
  • H301 Toxic if swallowed 吞食有毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H300+330
  • H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment
  • Faceshields, Gloves, Goggles, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSED1925000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 如果食入:立即呼叫中毒控制中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261305+351+338
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+330+331+310
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P261280301+310305+351+338310
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P210261264273280301+310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. 如果吞咽:漱口。不要催吐。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P301+310+331
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P308+311
  • P304+340+310
  • P241+242+243
  • P303+361+353+310+363
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
Signal word
  • Danger
Storage condition
  • Moisture Sensitive
  • 0-10
  • 0-10°C
  • 储存温度 2-8℃; 充氩保存
  • 2-8°C
UN Number
  • UN2927
  • 2924
  • 3265
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S8 Keep container dry 保持容器干燥;
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
  • S1 Keep locked up 上锁;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S25 Avoid contact with eyes 避免眼睛接触;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R14 Reacts violently with water 遇水会猛烈反应
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
  • R10 Flammable 易燃
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R11 Highly flammable 非常易燃
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R34 Causes burns 会导致灼伤
  • R48/20
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R50/53
  • R51/53
Packing GroupII
Hazard Class3/8
Warnings
  • 危化品目录(2015)
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 20 ppm/7H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Skin and Appendages - dermatitis, other (after systemic exposure)
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2541 ppm/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   42,417,1977

  • ⑴.常温常压下为无色发烟液体或气体,有强烈臭味,易潮解。对眼睛、皮肤、粘膜和上呼吸道有强烈的腐蚀作用。吸入后可因喉、支气管的痉挛、水肿,化学性肺炎、肺水肿而致死。中毒表现有烧灼感、咳嗽、喘息、喉炎、气短、头痛、恶心和呕吐。 ⑵. 化学反应活性很高,遇水分解生成氯化氢和硼酸,并放出大量热量。在湿空气中因水解而生成烟雾。与铜及其合金有可能生成具有爆炸性的氯乙炔。遇潮气时对大多数金属有强腐蚀性,也能腐蚀玻璃等。三氯化硼反应能力较强,能形成多种配位化合物,具有较高的热力学稳定性,但在放电作用下,会分解形成低价的 用于制备脂肪酸甲酯以及用于三酸甘油酯的酯交换反应。
  • 1. Kawaguchi, M. et al. Chem. Mater. 8 , 1197, (1996)
  • 2. McGinnis, M.B. et al. J. Org. Chem. 61 , 3496, (1996)
  • Merck 14 ,1348
  • Fieser 1 ,67 / Fieser 2 ,34 / Fieser 3 ,31 / Fieser 4 ,42 / Fieser 5 ,50 / Fieser 6 ,65 / Fieser 9 ,62 / Fieser 12 ,65 / Fieser 13 ,43 / Fieser 14 ,54 / Fieser 15 ,44
  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and s
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。