Phenyl Chloroformate 氯甲酸苯酯

规格: 99%
CAS: 1885-14-9
产品编号: H12788
MDL: MFCD00000637
品牌: INFI
Chemical NamePhenyl Carbonochloridate
Synonym Phenyl Chloroformate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number1885-14-9
EC Number217-547-8
Beilstein Registry Number606778
MDL NumberMFCD00000637
PubChem Substance ID15891
Reaxys-RN606778
Chemical Name Translation氯甲酸苯酯
LabNetwork Molecule IDLN00226528
InChIInChI=1S/C7H5ClO2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H
Canonical SMILESClC(=O)Oc1ccccc1
GHS Symbol
Signal word Danger
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Risk Statements
    • R22 Harmful if swallowed 吞咽有害
    • R26 Very toxic by inhalation 吸入极毒
    • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
    • R34 Causes burns 会导致灼伤
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R37 Irritating to respiratory system 刺激呼吸道
    • R38 Irritating to skin 刺激皮肤
    • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P234 Keep only in original container. 只保留在原来的容器中。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P264+P265
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
      • P301+P312
      • P301+P317
      • P301+P330+P331
      • P301+P330+P331+P310
      • P302+P352
      • P302+P361+P354
      • P303+P361+P353
      • P303+P361+P353+P310+P363
      • P304+P340
      • P304+P340+P310
      • P305+P351+P338
      • P305+P351+P338+P310
      • P305+P354+P338
      • P308+P313
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
      • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
      • P316
      • P317
      • P319
      • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P330 Rinse mouth. 漱口
      • P332+P313
      • P332+P317
      • P333+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P362+P364
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P370+P378
      • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
      • P403 Store in a well-ventilated place. 储存在通风良好的地方。
      • P403+P233
      • P403+P235
      • P404 Store in a closed container. 贮存于密闭容器中。
      • P405 Store locked up. 上锁保管。
      • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H227 Combustible liquid 可燃液体
        • H290 May be corrosive to metals 可能腐蚀金属。
        • H302 Harmful if swallowed 吞食有害
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H315 Causes skin irritation 会刺激皮肤
        • H317 May cause an allergic skin reaction 可能导致皮肤过敏
        • H318 Causes serious eye damage 严重伤害眼睛
        • H330 Fatal if inhaled 吸入致命
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          RTECSFG3850000
          Packing GroupII
          UN Number 2746 UN 2746 6.1/PG 2
          Storage condition 2-8°C Moisture Sensitive N/A N/A℃ No Data Available Refrigerator {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {
          Hazard Codes 6.1 T+
          Hazard Class6.1/8
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 用于有机合成产品的中间体。
        • {ALF} Also used in the cleavage of tertiary amines: J. Chem. Soc. (C), 2015 (1967); cf Ethyl­ chloroformate, L06311, and 1-Chloroethyl­ chloroformate, L14197. Review: Synthesis, 1 (1989).
        • {ALF} Precursor of phenyl mixed anhydrides, which can be used, e.g. in peptide coupling reactions.
        • {uni_hamburg} Short: III/20b
        • {uni_hamburg} Short: EINECS
        • {ALF} Reagent for dehydration of primary amides to nitriles under mild conditions: Indian J. Chem., 40B, 722 (2001).
        • {ALD} Beilstein: 6,IV,629
          • 1885-14-9 H12788 Phenyl Chloroformate 氯甲酸苯酯

          化学属性

          Mol. FormulaC7H5ClO2
          Mol. Weight156.57
          Density1.228
          Refractive index1.5100 to 1.5130
          Vapor Density1 (vs air)
          Boiling Point74-75 °C/13 mmHg(lit.)
          Vapor Pressure1.22 psi ( 20 °C)
          Flash Point75.56°C
          TSCAYes
          Melting Point-28 °C
          Solubility水解
          Stability对湿度敏感,对热敏感

          *以上化合物性质及应用等信息仅供参考